Please do not share screenshots of configurations, you are a developer you should know that.
Anyway probably your item is not a custom block that's why you cannot get it. If you get it using CustomItem.getInstance
it will work since the item exists.
You have to add the block configuration part.
Follow the wiki. https://itemsadder.devs.beer/plugin-usage/adding-content/block
Another reason could be that the block item didn't load for some reason.
It's impossible to help you more than that.